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    <link:label id="lab_deo_MarketingExpenses_documentation_en" xlink:label="lab_deo_MarketingExpenses" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Marketing Expenses</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_MarketingExpenses" xlink:href="213800ZVIELEA55JMJ32-2026-06-30.xsd#deo_MarketingExpenses"/>
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    <link:label id="lab_ifrs-full_CashFlowsFromUsedInInvestingActivities_019e449b-9276-7f0c-a924-51423c2e4f8b_totalLabel_en" xlink:label="lab_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Cash flows from (used in) investing activities</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:href="https://xbrl.ifrs.org/taxonomy/2024-03-27/full_ifrs/full_ifrs-cor_2024-03-27.xsd#ifrs-full_CashFlowsFromUsedInInvestingActivities"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:to="lab_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:type="arc" order="1"/>
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    <link:label id="lab_deo_ProceedsFromUnclaimedDividendsAndShareForfeiture_documentation_en" xlink:label="lab_deo_ProceedsFromUnclaimedDividendsAndShareForfeiture" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Proceeds From Unclaimed Dividends And Share Forfeiture</link:label>
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    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ProceedsFromUnclaimedDividendsAndShareForfeiture" xlink:to="lab_deo_ProceedsFromUnclaimedDividendsAndShareForfeiture" xlink:type="arc" order="1"/>
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    <link:label id="lab_deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember_documentation_en" xlink:label="lab_deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Opening Balance After Adjustment, Cumulative Effect At Date Of Adjustment</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember" xlink:href="213800ZVIELEA55JMJ32-2026-06-30.xsd#deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember"/>
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    <link:label id="lab_deo_CashAndCashEquivalentsOverdraftClassifiedAsPartOfDisposalGroupHeldForSale_label_en" xlink:label="lab_deo_CashAndCashEquivalentsOverdraftClassifiedAsPartOfDisposalGroupHeldForSale" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Cash And Cash Equivalents/(Overdraft) Classified As Part Of Disposal Group Held For Sale</link:label>
    <link:label id="lab_deo_CashAndCashEquivalentsOverdraftClassifiedAsPartOfDisposalGroupHeldForSale_documentation_en" xlink:label="lab_deo_CashAndCashEquivalentsOverdraftClassifiedAsPartOfDisposalGroupHeldForSale" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Cash And Cash Equivalents/(Overdraft) Classified As Part Of Disposal Group Held For Sale</link:label>
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    <link:label id="lab_deo_CumulativeEffectAtDateOfAdjustmentMember_label_en" xlink:label="lab_deo_CumulativeEffectAtDateOfAdjustmentMember" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Cumulative Effect At Date Of Adjustment [Member]</link:label>
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    <link:label id="lab_ifrs-full_CashFlowsFromUsedInOperatingActivities_019e449b-9276-7d83-ba69-6680c780eeaa_totalLabel_en" xlink:label="lab_ifrs-full_CashFlowsFromUsedInOperatingActivities" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Cash flows from (used in) operating activities</link:label>
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