<?xml version="1.0" encoding="UTF-8"?>

<!--XBRL Document Created with the Workiva Platform-->
<!--Copyright 2024 Workiva-->
<!--r:c55511a1-3587-45fd-ac83-387c1767de7a,g:d89d3b42-458c-41c0-9a83-5259c6af70ed-->
<link:linkbase xmlns:link="http://www.xbrl.org/2003/linkbase" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.xbrl.org/2003/linkbase http://www.xbrl.org/2003/xbrl-linkbase-2003-12-31.xsd">
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedPeriodStartLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedPeriodStartLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/netLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/net-2009-12-16.xsd#netLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedNetLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedNetLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedTerseLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedTerseLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedPeriodEndLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedPeriodEndLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedTotalLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedTotalLabel"/>
  <link:labelLink xlink:role="http://www.xbrl.org/2003/role/link" xlink:type="extended">
    <link:label id="lab_deo_ReserveOfCashFlowHedgesAndExchangeDifferencesOnTranslationMember_label_en" xlink:label="lab_deo_ReserveOfCashFlowHedgesAndExchangeDifferencesOnTranslationMember" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Reserve Of Cash Flow Hedges And Exchange Differences On Translation [Member]</link:label>
    <link:label id="lab_deo_ReserveOfCashFlowHedgesAndExchangeDifferencesOnTranslationMember_documentation_en" xlink:label="lab_deo_ReserveOfCashFlowHedgesAndExchangeDifferencesOnTranslationMember" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Reserve of cash flow hedges and exchange differences on translation.</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ReserveOfCashFlowHedgesAndExchangeDifferencesOnTranslationMember" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ReserveOfCashFlowHedgesAndExchangeDifferencesOnTranslationMember"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ReserveOfCashFlowHedgesAndExchangeDifferencesOnTranslationMember" xlink:to="lab_deo_ReserveOfCashFlowHedgesAndExchangeDifferencesOnTranslationMember" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_ProceedsFromDisposalsOfPropertyPlantAndEquipmentAndComputerSoftware_label_en" xlink:label="lab_deo_ProceedsFromDisposalsOfPropertyPlantAndEquipmentAndComputerSoftware" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Proceeds From Disposals Of Property, Plant And Equipment And Computer Software</link:label>
    <link:label id="lab_deo_ProceedsFromDisposalsOfPropertyPlantAndEquipmentAndComputerSoftware_documentation_en" xlink:label="lab_deo_ProceedsFromDisposalsOfPropertyPlantAndEquipmentAndComputerSoftware" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Proceeds From Disposals Of Property, Plant And Equipment And Computer Software</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ProceedsFromDisposalsOfPropertyPlantAndEquipmentAndComputerSoftware" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ProceedsFromDisposalsOfPropertyPlantAndEquipmentAndComputerSoftware"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ProceedsFromDisposalsOfPropertyPlantAndEquipmentAndComputerSoftware" xlink:to="lab_deo_ProceedsFromDisposalsOfPropertyPlantAndEquipmentAndComputerSoftware" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_NetSales_2e1d69de-c1db-4358-99a2-8fc2e1ea1686_totalLabel_en" xlink:label="lab_deo_NetSales" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Net Sales</link:label>
    <link:label id="lab_deo_NetSales_label_en" xlink:label="lab_deo_NetSales" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Net Sales</link:label>
    <link:label id="lab_deo_NetSales_documentation_en" xlink:label="lab_deo_NetSales" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Sales Less Excise Duties</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_NetSales" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_NetSales"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_NetSales" xlink:to="lab_deo_NetSales" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_PaymentsToAcquireOrRedeemEntitysSharesForShareSchemes_label_en" xlink:label="lab_deo_PaymentsToAcquireOrRedeemEntitysSharesForShareSchemes" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Payments To Acquire Or Redeem Entitys Shares For Share Schemes</link:label>
    <link:label id="lab_deo_PaymentsToAcquireOrRedeemEntitysSharesForShareSchemes_documentation_en" xlink:label="lab_deo_PaymentsToAcquireOrRedeemEntitysSharesForShareSchemes" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Payments To Acquire Or Redeem Entitys Shares For Share Schemes</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_PaymentsToAcquireOrRedeemEntitysSharesForShareSchemes" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_PaymentsToAcquireOrRedeemEntitysSharesForShareSchemes"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_PaymentsToAcquireOrRedeemEntitysSharesForShareSchemes" xlink:to="lab_deo_PaymentsToAcquireOrRedeemEntitysSharesForShareSchemes" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncreaseDecreaseDueToAdjustmentRelatedToHyperinflationEquityMember_label_en" xlink:label="lab_deo_IncreaseDecreaseDueToAdjustmentRelatedToHyperinflationEquityMember" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Increase (Decrease) Due To Adjustment Related To Hyperinflation, Equity [Member]</link:label>
    <link:label id="lab_deo_IncreaseDecreaseDueToAdjustmentRelatedToHyperinflationEquityMember_documentation_en" xlink:label="lab_deo_IncreaseDecreaseDueToAdjustmentRelatedToHyperinflationEquityMember" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Increase (Decrease) Due To Adjustment Related To Hyperinflation, Equity</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncreaseDecreaseDueToAdjustmentRelatedToHyperinflationEquityMember" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncreaseDecreaseDueToAdjustmentRelatedToHyperinflationEquityMember"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncreaseDecreaseDueToAdjustmentRelatedToHyperinflationEquityMember" xlink:to="lab_deo_IncreaseDecreaseDueToAdjustmentRelatedToHyperinflationEquityMember" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfDisposals_label_en" xlink:label="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfDisposals" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Exchange Gain (Loss) Recycled To The Income Statement On Translation Of Foreign Operations In Respect Of Disposals</link:label>
    <link:label id="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfDisposals_documentation_en" xlink:label="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfDisposals" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Exchange Gain (Loss) Recycled To The Income Statement On Translation Of Foreign Operations In Respect Of Disposals</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfDisposals" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfDisposals"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfDisposals" xlink:to="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfDisposals" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncreaseDecreaseThroughShareBasedPaymentsAndPurchaseOfTreasurySharesSubsidiaries_label_en" xlink:label="lab_deo_IncreaseDecreaseThroughShareBasedPaymentsAndPurchaseOfTreasurySharesSubsidiaries" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Share Based Payments And Purchase Of Treasury Shares, Subsidiaries</link:label>
    <link:label id="lab_deo_IncreaseDecreaseThroughShareBasedPaymentsAndPurchaseOfTreasurySharesSubsidiaries_documentation_en" xlink:label="lab_deo_IncreaseDecreaseThroughShareBasedPaymentsAndPurchaseOfTreasurySharesSubsidiaries" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Share Based Payments And Purchase Of Treasury Shares, Subsidiaries</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncreaseDecreaseThroughShareBasedPaymentsAndPurchaseOfTreasurySharesSubsidiaries" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncreaseDecreaseThroughShareBasedPaymentsAndPurchaseOfTreasurySharesSubsidiaries"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncreaseDecreaseThroughShareBasedPaymentsAndPurchaseOfTreasurySharesSubsidiaries" xlink:to="lab_deo_IncreaseDecreaseThroughShareBasedPaymentsAndPurchaseOfTreasurySharesSubsidiaries" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansInRespectOfAssociatesEquity_label_en" xlink:label="lab_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansInRespectOfAssociatesEquity" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Share-Based Payment Transactions, Incentive Plans In Respect Of Associates, Equity</link:label>
    <link:label id="lab_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansInRespectOfAssociatesEquity_documentation_en" xlink:label="lab_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansInRespectOfAssociatesEquity" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Share-Based Payment Transactions, Incentive Plans In Respect Of Associates, Equity</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansInRespectOfAssociatesEquity" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansInRespectOfAssociatesEquity"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansInRespectOfAssociatesEquity" xlink:to="lab_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansInRespectOfAssociatesEquity" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsAssociatesAndJointVentures_label_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsAssociatesAndJointVentures" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Exchange Differences On Translation Of Foreign Operations, Associates And Joint Ventures</link:label>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsAssociatesAndJointVentures_documentation_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsAssociatesAndJointVentures" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Exchange Differences On Translation Of Foreign Operations, Associates And Joint Ventures</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsAssociatesAndJointVentures" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsAssociatesAndJointVentures"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsAssociatesAndJointVentures" xlink:to="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsAssociatesAndJointVentures" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_ShareBuybackLiability_label_en" xlink:label="lab_deo_ShareBuybackLiability" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Share Buyback Liability</link:label>
    <link:label id="lab_deo_ShareBuybackLiability_documentation_en" xlink:label="lab_deo_ShareBuybackLiability" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Share Buyback Liability</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ShareBuybackLiability" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ShareBuybackLiability"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ShareBuybackLiability" xlink:to="lab_deo_ShareBuybackLiability" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesTransactionExposureHedging_label_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesTransactionExposureHedging" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Cash Flow Hedges, Transaction Exposure Hedging</link:label>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesTransactionExposureHedging_documentation_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesTransactionExposureHedging" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Cash Flow Hedges, Transaction Exposure Hedging</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesTransactionExposureHedging" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesTransactionExposureHedging"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesTransactionExposureHedging" xlink:to="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesTransactionExposureHedging" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncreaseDecreaseThroughRetranslationImpactOfOpeningBalancesEquity_label_en" xlink:label="lab_deo_IncreaseDecreaseThroughRetranslationImpactOfOpeningBalancesEquity" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Retranslation Impact Of Opening Balances, Equity</link:label>
    <link:label id="lab_deo_IncreaseDecreaseThroughRetranslationImpactOfOpeningBalancesEquity_documentation_en" xlink:label="lab_deo_IncreaseDecreaseThroughRetranslationImpactOfOpeningBalancesEquity" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Retranslation Impact Of Opening Balances, Equity</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncreaseDecreaseThroughRetranslationImpactOfOpeningBalancesEquity" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncreaseDecreaseThroughRetranslationImpactOfOpeningBalancesEquity"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncreaseDecreaseThroughRetranslationImpactOfOpeningBalancesEquity" xlink:to="lab_deo_IncreaseDecreaseThroughRetranslationImpactOfOpeningBalancesEquity" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxTransactionExposureHedging_label_en" xlink:label="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxTransactionExposureHedging" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Reclassification Adjustments On Cash Flow Hedges, Before Tax, Transaction Exposure Hedging</link:label>
    <link:label id="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxTransactionExposureHedging_documentation_en" xlink:label="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxTransactionExposureHedging" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Reclassification Adjustments On Cash Flow Hedges, Before Tax, Transaction Exposure Hedging</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxTransactionExposureHedging" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxTransactionExposureHedging"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxTransactionExposureHedging" xlink:to="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxTransactionExposureHedging" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_AdjustmentsForDepreciationAmortisationImpairmentDividendAndOtherItems_d9c97910-e864-4119-b592-544cbb122895_totalLabel_en" xlink:label="lab_deo_AdjustmentsForDepreciationAmortisationImpairmentDividendAndOtherItems" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Adjustments For Depreciation Amortisation Impairment Dividend And Other Items</link:label>
    <link:label id="lab_deo_AdjustmentsForDepreciationAmortisationImpairmentDividendAndOtherItems_label_en" xlink:label="lab_deo_AdjustmentsForDepreciationAmortisationImpairmentDividendAndOtherItems" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Adjustments For Depreciation, Amortisation, Impairment Dividend And Other Items</link:label>
    <link:label id="lab_deo_AdjustmentsForDepreciationAmortisationImpairmentDividendAndOtherItems_documentation_en" xlink:label="lab_deo_AdjustmentsForDepreciationAmortisationImpairmentDividendAndOtherItems" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">The net total of Depreciation, amortisation and impairment; Dividend received, Post employment payments and Other items reported as Operating Cash flow.</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_AdjustmentsForDepreciationAmortisationImpairmentDividendAndOtherItems" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_AdjustmentsForDepreciationAmortisationImpairmentDividendAndOtherItems"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_AdjustmentsForDepreciationAmortisationImpairmentDividendAndOtherItems" xlink:to="lab_deo_AdjustmentsForDepreciationAmortisationImpairmentDividendAndOtherItems" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncreaseDecreaseThroughTaxesOnPurchaseOfNonControllingInterests_label_en" xlink:label="lab_deo_IncreaseDecreaseThroughTaxesOnPurchaseOfNonControllingInterests" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Taxes On Purchase Of Non-Controlling Interests</link:label>
    <link:label id="lab_deo_IncreaseDecreaseThroughTaxesOnPurchaseOfNonControllingInterests_documentation_en" xlink:label="lab_deo_IncreaseDecreaseThroughTaxesOnPurchaseOfNonControllingInterests" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Taxes On Purchase Of Non-Controlling Interests</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncreaseDecreaseThroughTaxesOnPurchaseOfNonControllingInterests" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncreaseDecreaseThroughTaxesOnPurchaseOfNonControllingInterests"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncreaseDecreaseThroughTaxesOnPurchaseOfNonControllingInterests" xlink:to="lab_deo_IncreaseDecreaseThroughTaxesOnPurchaseOfNonControllingInterests" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansGroup_label_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansGroup" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Gains (Losses) On Remeasurements Of Defined Benefit Plans, Group</link:label>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansGroup_documentation_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansGroup" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Gains (Losses) On Remeasurements Of Defined Benefit Plans, Group</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansGroup" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansGroup"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansGroup" xlink:to="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansGroup" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesAssociatesAndJointVentures_label_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesAssociatesAndJointVentures" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Cash Flow Hedges, Associates And Joint Ventures</link:label>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesAssociatesAndJointVentures_documentation_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesAssociatesAndJointVentures" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Cash Flow Hedges, Associates And Joint Ventures</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesAssociatesAndJointVentures" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesAssociatesAndJointVentures"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesAssociatesAndJointVentures" xlink:to="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesAssociatesAndJointVentures" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_MarketingExpenses_label_en" xlink:label="lab_deo_MarketingExpenses" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Marketing Expenses</link:label>
    <link:label id="lab_deo_MarketingExpenses_documentation_en" xlink:label="lab_deo_MarketingExpenses" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Marketing Expenses</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_MarketingExpenses" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_MarketingExpenses"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_MarketingExpenses" xlink:to="lab_deo_MarketingExpenses" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_IncreaseDecreaseInWorkingCapital_8bcecaab-9180-4602-bbfa-8b42e5433dd3_totalLabel_en" xlink:label="lab_ifrs-full_IncreaseDecreaseInWorkingCapital" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Increase (decrease) in working capital</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_IncreaseDecreaseInWorkingCapital" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_IncreaseDecreaseInWorkingCapital"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_IncreaseDecreaseInWorkingCapital" xlink:to="lab_ifrs-full_IncreaseDecreaseInWorkingCapital" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesHedgeOfForeignCurrencyDebt_label_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesHedgeOfForeignCurrencyDebt" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Cash Flow Hedges, Hedge Of Foreign Currency Debt</link:label>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesHedgeOfForeignCurrencyDebt_documentation_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesHedgeOfForeignCurrencyDebt" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Cash Flow Hedges, Hedge Of Foreign Currency Debt</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesHedgeOfForeignCurrencyDebt" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesHedgeOfForeignCurrencyDebt"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesHedgeOfForeignCurrencyDebt" xlink:to="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesHedgeOfForeignCurrencyDebt" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_MovementsInLoansAndOtherInvestments_label_en" xlink:label="lab_deo_MovementsInLoansAndOtherInvestments" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Movements In Loans And Other Investments</link:label>
    <link:label id="lab_deo_MovementsInLoansAndOtherInvestments_documentation_en" xlink:label="lab_deo_MovementsInLoansAndOtherInvestments" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Movements In Loans And Other Investments</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_MovementsInLoansAndOtherInvestments" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_MovementsInLoansAndOtherInvestments"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_MovementsInLoansAndOtherInvestments" xlink:to="lab_deo_MovementsInLoansAndOtherInvestments" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncomeTaxChargeCreditRelatingToExchangeDifferencesOnTranslationOfForeignOperationsAndNetInvestmentHedgesOtherComprehensiveIncomeGroup_label_en" xlink:label="lab_deo_IncomeTaxChargeCreditRelatingToExchangeDifferencesOnTranslationOfForeignOperationsAndNetInvestmentHedgesOtherComprehensiveIncomeGroup" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Income Tax Charge (Credit) Relating To Exchange Differences On Translation Of Foreign Operations And Net Investment Hedges Other Comprehensive Income, Group</link:label>
    <link:label id="lab_deo_IncomeTaxChargeCreditRelatingToExchangeDifferencesOnTranslationOfForeignOperationsAndNetInvestmentHedgesOtherComprehensiveIncomeGroup_documentation_en" xlink:label="lab_deo_IncomeTaxChargeCreditRelatingToExchangeDifferencesOnTranslationOfForeignOperationsAndNetInvestmentHedgesOtherComprehensiveIncomeGroup" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Income Tax Charge (Credit) Relating To Exchange Differences On Translation Of Foreign Operations And Net Investment Hedges Other Comprehensive Income, Group</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncomeTaxChargeCreditRelatingToExchangeDifferencesOnTranslationOfForeignOperationsAndNetInvestmentHedgesOtherComprehensiveIncomeGroup" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncomeTaxChargeCreditRelatingToExchangeDifferencesOnTranslationOfForeignOperationsAndNetInvestmentHedgesOtherComprehensiveIncomeGroup"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncomeTaxChargeCreditRelatingToExchangeDifferencesOnTranslationOfForeignOperationsAndNetInvestmentHedgesOtherComprehensiveIncomeGroup" xlink:to="lab_deo_IncomeTaxChargeCreditRelatingToExchangeDifferencesOnTranslationOfForeignOperationsAndNetInvestmentHedgesOtherComprehensiveIncomeGroup" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_CashFlowsFromUsedInOperatingActivities_f2013eb4-bcde-481a-9a3b-0104e35d108b_totalLabel_en" xlink:label="lab_ifrs-full_CashFlowsFromUsedInOperatingActivities" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Cash flows from (used in) operating activities</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_CashFlowsFromUsedInOperatingActivities" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CashFlowsFromUsedInOperatingActivities"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_CashFlowsFromUsedInOperatingActivities" xlink:to="lab_ifrs-full_CashFlowsFromUsedInOperatingActivities" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember_label_en" xlink:label="lab_deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Opening Balance After Adjustment, Cumulative Effect At Date Of Adjustment [Member]</link:label>
    <link:label id="lab_deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember_documentation_en" xlink:label="lab_deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Opening Balance After Adjustment, Cumulative Effect At Date Of Adjustment</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember" xlink:to="lab_deo_OpeningBalanceAfterAdjustmentCumulativeEffectAtDateOfAdjustmentMember" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_InterestAndIncomeTaxesPaidReceivedClassifiedAsOperatingActivities_16317e56-83bd-4a75-ab9d-20eebb564a8d_totalLabel_en" xlink:label="lab_deo_InterestAndIncomeTaxesPaidReceivedClassifiedAsOperatingActivities" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Interest And Income Taxes Paid (Received), Classified As Operating Activities</link:label>
    <link:label id="lab_deo_InterestAndIncomeTaxesPaidReceivedClassifiedAsOperatingActivities_label_en" xlink:label="lab_deo_InterestAndIncomeTaxesPaidReceivedClassifiedAsOperatingActivities" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Interest And Income Taxes Paid (Received), Classified As Operating Activities</link:label>
    <link:label id="lab_deo_InterestAndIncomeTaxesPaidReceivedClassifiedAsOperatingActivities_documentation_en" xlink:label="lab_deo_InterestAndIncomeTaxesPaidReceivedClassifiedAsOperatingActivities" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Interest And Income Taxes Paid (Received), Classified As Operating Activities</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_InterestAndIncomeTaxesPaidReceivedClassifiedAsOperatingActivities" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_InterestAndIncomeTaxesPaidReceivedClassifiedAsOperatingActivities"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_InterestAndIncomeTaxesPaidReceivedClassifiedAsOperatingActivities" xlink:to="lab_deo_InterestAndIncomeTaxesPaidReceivedClassifiedAsOperatingActivities" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCostOfHedging_label_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCostOfHedging" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Cash Flow Hedges, Cost Of Hedging</link:label>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCostOfHedging_documentation_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCostOfHedging" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Cash Flow Hedges, Cost Of Hedging</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCostOfHedging" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCostOfHedging"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCostOfHedging" xlink:to="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCostOfHedging" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_NonOperatingGainsLosses_label_en" xlink:label="lab_deo_NonOperatingGainsLosses" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Non Operating Gains (Losses)</link:label>
    <link:label id="lab_deo_NonOperatingGainsLosses_documentation_en" xlink:label="lab_deo_NonOperatingGainsLosses" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Non Operating Gains (Losses)</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_NonOperatingGainsLosses" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_NonOperatingGainsLosses"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_NonOperatingGainsLosses" xlink:to="lab_deo_NonOperatingGainsLosses" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_CumulativeEffectAtDateOfAdjustmentMember_label_en" xlink:label="lab_deo_CumulativeEffectAtDateOfAdjustmentMember" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Cumulative Effect At Date Of Adjustment [Member]</link:label>
    <link:label id="lab_deo_CumulativeEffectAtDateOfAdjustmentMember_documentation_en" xlink:label="lab_deo_CumulativeEffectAtDateOfAdjustmentMember" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Cumulative Effect At Date Of Adjustment</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_CumulativeEffectAtDateOfAdjustmentMember" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_CumulativeEffectAtDateOfAdjustmentMember"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_CumulativeEffectAtDateOfAdjustmentMember" xlink:to="lab_deo_CumulativeEffectAtDateOfAdjustmentMember" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_CashFlowsFromUsedInFinancingActivities_43cfc53f-a9c3-41e6-b558-8a34e89804fd_totalLabel_en" xlink:label="lab_ifrs-full_CashFlowsFromUsedInFinancingActivities" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Cash flows from (used in) financing activities</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_CashFlowsFromUsedInFinancingActivities" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CashFlowsFromUsedInFinancingActivities"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_CashFlowsFromUsedInFinancingActivities" xlink:to="lab_ifrs-full_CashFlowsFromUsedInFinancingActivities" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansAssociatesAndJointVentures_label_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansAssociatesAndJointVentures" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Gains (Losses) On Remeasurements Of Defined Benefit Plans, Associates And Joint Ventures</link:label>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansAssociatesAndJointVentures_documentation_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansAssociatesAndJointVentures" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Gains (Losses) On Remeasurements Of Defined Benefit Plans, Associates And Joint Ventures</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansAssociatesAndJointVentures" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansAssociatesAndJointVentures"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansAssociatesAndJointVentures" xlink:to="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansAssociatesAndJointVentures" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_GrossProfit_355f7186-227e-41e2-8649-0485b0a706ee_totalLabel_en" xlink:label="lab_ifrs-full_GrossProfit" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Gross profit</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_GrossProfit" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_GrossProfit"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_GrossProfit" xlink:to="lab_ifrs-full_GrossProfit" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_AssetsIncludedInDisposalGroupsClassifiedAsHeldForSale_label_en" xlink:label="lab_deo_AssetsIncludedInDisposalGroupsClassifiedAsHeldForSale" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Assets Included In Disposal Groups Classified As Held For Sale</link:label>
    <link:label id="lab_deo_AssetsIncludedInDisposalGroupsClassifiedAsHeldForSale_documentation_en" xlink:label="lab_deo_AssetsIncludedInDisposalGroupsClassifiedAsHeldForSale" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Assets Included In Disposal Groups Classified As Held For Sale</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_AssetsIncludedInDisposalGroupsClassifiedAsHeldForSale" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_AssetsIncludedInDisposalGroupsClassifiedAsHeldForSale"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_AssetsIncludedInDisposalGroupsClassifiedAsHeldForSale" xlink:to="lab_deo_AssetsIncludedInDisposalGroupsClassifiedAsHeldForSale" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCostOfHedging_label_en" xlink:label="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCostOfHedging" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Reclassification Adjustments On Cash Flow Hedges, Before Tax, Cost Of Hedging</link:label>
    <link:label id="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCostOfHedging_documentation_en" xlink:label="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCostOfHedging" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Reclassification Adjustments On Cash Flow Hedges, Before Tax, Cost Of Hedging</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCostOfHedging" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCostOfHedging"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCostOfHedging" xlink:to="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCostOfHedging" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_CashAndCashEquivalentsIfDifferentFromStatementOfFinancialPosition_1a1777bc-297c-415c-a75e-b4d1f27f59aa_periodStartLabel_en" xlink:label="lab_ifrs-full_CashAndCashEquivalentsIfDifferentFromStatementOfFinancialPosition" xlink:role="http://www.xbrl.org/2003/role/periodStartLabel" xlink:type="resource" xml:lang="en">Net cash and cash equivalents at beginning of the year</link:label>
    <link:label id="lab_ifrs-full_CashAndCashEquivalentsIfDifferentFromStatementOfFinancialPosition_e05e8ed1-0f1d-4af9-b91f-5fef6430e365_periodEndLabel_en" xlink:label="lab_ifrs-full_CashAndCashEquivalentsIfDifferentFromStatementOfFinancialPosition" xlink:role="http://www.xbrl.org/2003/role/periodEndLabel" xlink:type="resource" xml:lang="en">Net cash and cash equivalents at end of the year</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_CashAndCashEquivalentsIfDifferentFromStatementOfFinancialPosition" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CashAndCashEquivalentsIfDifferentFromStatementOfFinancialPosition"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_CashAndCashEquivalentsIfDifferentFromStatementOfFinancialPosition" xlink:to="lab_ifrs-full_CashAndCashEquivalentsIfDifferentFromStatementOfFinancialPosition" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_ChangesInCashAndCashEquivalentsAbstract_label_en" xlink:label="lab_deo_ChangesInCashAndCashEquivalentsAbstract" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Changes In Cash And Cash Equivalents [Abstract]</link:label>
    <link:label id="lab_deo_ChangesInCashAndCashEquivalentsAbstract_documentation_en" xlink:label="lab_deo_ChangesInCashAndCashEquivalentsAbstract" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Changes In Cash And Cash Equivalents</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ChangesInCashAndCashEquivalentsAbstract" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ChangesInCashAndCashEquivalentsAbstract"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ChangesInCashAndCashEquivalentsAbstract" xlink:to="lab_deo_ChangesInCashAndCashEquivalentsAbstract" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansNonControllingInterests_label_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansNonControllingInterests" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Gains (Losses) On Remeasurements Of Defined Benefit Plans, Non-Controlling Interests</link:label>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansNonControllingInterests_documentation_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansNonControllingInterests" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Gains (Losses) On Remeasurements Of Defined Benefit Plans, Non-Controlling Interests</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansNonControllingInterests" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansNonControllingInterests"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansNonControllingInterests" xlink:to="lab_deo_OtherComprehensiveIncomeBeforeTaxGainsLossesOnRemeasurementsOfDefinedBenefitPlansNonControllingInterests" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncreaseDecreaseInEquityThoughChangeInFairValueOfPutOption_label_en" xlink:label="lab_deo_IncreaseDecreaseInEquityThoughChangeInFairValueOfPutOption" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Increase (Decrease) In Equity Though Change In Fair Value Of Put Option</link:label>
    <link:label id="lab_deo_IncreaseDecreaseInEquityThoughChangeInFairValueOfPutOption_documentation_en" xlink:label="lab_deo_IncreaseDecreaseInEquityThoughChangeInFairValueOfPutOption" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Increase (Decrease) In Equity Though Change In Fair Value Of Put Option</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncreaseDecreaseInEquityThoughChangeInFairValueOfPutOption" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncreaseDecreaseInEquityThoughChangeInFairValueOfPutOption"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncreaseDecreaseInEquityThoughChangeInFairValueOfPutOption" xlink:to="lab_deo_IncreaseDecreaseInEquityThoughChangeInFairValueOfPutOption" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncomeTaxChargeCreditRelatingToTaxOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome_label_en" xlink:label="lab_deo_IncomeTaxChargeCreditRelatingToTaxOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Income Tax Charge (Credit) Relating To Tax On Hyperinflation Adjustments Included In Other Comprehensive Income</link:label>
    <link:label id="lab_deo_IncomeTaxChargeCreditRelatingToTaxOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome_documentation_en" xlink:label="lab_deo_IncomeTaxChargeCreditRelatingToTaxOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Income Tax Charge (Credit) Relating To Tax On Hyperinflation Adjustments Included In Other Comprehensive Income</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncomeTaxChargeCreditRelatingToTaxOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncomeTaxChargeCreditRelatingToTaxOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncomeTaxChargeCreditRelatingToTaxOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome" xlink:to="lab_deo_IncomeTaxChargeCreditRelatingToTaxOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncomeTaxChargeCreditRelatingToTaxRateChangeOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome_label_en" xlink:label="lab_deo_IncomeTaxChargeCreditRelatingToTaxRateChangeOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Income Tax Charge (Credit) Relating To Tax Rate Change On Hyperinflation Adjustments Included In Other Comprehensive Income</link:label>
    <link:label id="lab_deo_IncomeTaxChargeCreditRelatingToTaxRateChangeOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome_documentation_en" xlink:label="lab_deo_IncomeTaxChargeCreditRelatingToTaxRateChangeOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Income Tax Charge (Credit) Relating To Tax Rate Change On Hyperinflation Adjustments Included In Other Comprehensive Income</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncomeTaxChargeCreditRelatingToTaxRateChangeOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncomeTaxChargeCreditRelatingToTaxRateChangeOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncomeTaxChargeCreditRelatingToTaxRateChangeOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome" xlink:to="lab_deo_IncomeTaxChargeCreditRelatingToTaxRateChangeOnHyperinflationAdjustmentsIncludedInOtherComprehensiveIncome" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_CashFlowsFromUsedInInvestingActivities_e42851dd-40b2-4151-b208-b3bc52cc64ec_totalLabel_en" xlink:label="lab_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Cash flows from (used in) investing activities</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CashFlowsFromUsedInInvestingActivities"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:to="lab_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_PropertyPlantAndEquipmentIncludingRightOfUseAssets_label_en" xlink:label="lab_deo_PropertyPlantAndEquipmentIncludingRightOfUseAssets" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Property, Plant And Equipment Including Right-Of-Use Assets</link:label>
    <link:label id="lab_deo_PropertyPlantAndEquipmentIncludingRightOfUseAssets_documentation_en" xlink:label="lab_deo_PropertyPlantAndEquipmentIncludingRightOfUseAssets" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Property, Plant And Equipment Including Right-Of-Use Assets</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_PropertyPlantAndEquipmentIncludingRightOfUseAssets" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_PropertyPlantAndEquipmentIncludingRightOfUseAssets"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_PropertyPlantAndEquipmentIncludingRightOfUseAssets" xlink:to="lab_deo_PropertyPlantAndEquipmentIncludingRightOfUseAssets" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncreaseDecreaseThroughAssociatesTransactionsWithNonControllingInterestEquity_label_en" xlink:label="lab_deo_IncreaseDecreaseThroughAssociatesTransactionsWithNonControllingInterestEquity" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Associates Transactions With Non Controlling Interest, Equity</link:label>
    <link:label id="lab_deo_IncreaseDecreaseThroughAssociatesTransactionsWithNonControllingInterestEquity_documentation_en" xlink:label="lab_deo_IncreaseDecreaseThroughAssociatesTransactionsWithNonControllingInterestEquity" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Associates Transactions With Non Controlling Interest, Equity</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncreaseDecreaseThroughAssociatesTransactionsWithNonControllingInterestEquity" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncreaseDecreaseThroughAssociatesTransactionsWithNonControllingInterestEquity"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncreaseDecreaseThroughAssociatesTransactionsWithNonControllingInterestEquity" xlink:to="lab_deo_IncreaseDecreaseThroughAssociatesTransactionsWithNonControllingInterestEquity" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsGroup_label_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsGroup" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Exchange Differences On Translation Of Foreign Operations, Group</link:label>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsGroup_documentation_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsGroup" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Exchange Differences On Translation Of Foreign Operations, Group</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsGroup" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsGroup"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsGroup" xlink:to="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsGroup" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCommodityPriceRiskHedging_label_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCommodityPriceRiskHedging" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Cash Flow Hedges, Commodity Price Risk Hedging</link:label>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCommodityPriceRiskHedging_documentation_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCommodityPriceRiskHedging" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Cash Flow Hedges, Commodity Price Risk Hedging</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCommodityPriceRiskHedging" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCommodityPriceRiskHedging"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCommodityPriceRiskHedging" xlink:to="lab_deo_OtherComprehensiveIncomeBeforeTaxCashFlowHedgesCommodityPriceRiskHedging" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_CumulativeEffectAtDateOfAdjustmentAxis_label_en" xlink:label="lab_deo_CumulativeEffectAtDateOfAdjustmentAxis" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Cumulative Effect At Date Of Adjustment [Axis]</link:label>
    <link:label id="lab_deo_CumulativeEffectAtDateOfAdjustmentAxis_documentation_en" xlink:label="lab_deo_CumulativeEffectAtDateOfAdjustmentAxis" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Cumulative Effect At Date Of Adjustment</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_CumulativeEffectAtDateOfAdjustmentAxis" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_CumulativeEffectAtDateOfAdjustmentAxis"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_CumulativeEffectAtDateOfAdjustmentAxis" xlink:to="lab_deo_CumulativeEffectAtDateOfAdjustmentAxis" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansOtherThanAssociatesEquity_label_en" xlink:label="lab_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansOtherThanAssociatesEquity" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Share-Based Payment Transactions, Incentive Plans Other Than Associates, Equity</link:label>
    <link:label id="lab_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansOtherThanAssociatesEquity_documentation_en" xlink:label="lab_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansOtherThanAssociatesEquity" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Share-Based Payment Transactions, Incentive Plans Other Than Associates, Equity</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansOtherThanAssociatesEquity" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansOtherThanAssociatesEquity"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansOtherThanAssociatesEquity" xlink:to="lab_deo_IncreaseDecreaseThroughShareBasedPaymentTransactionsIncentivePlansOtherThanAssociatesEquity" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncomeTaxChargeCreditRelatingToHyperinflationAdjustmentIncludedInOtherComprehensiveIncome_label_en" xlink:label="lab_deo_IncomeTaxChargeCreditRelatingToHyperinflationAdjustmentIncludedInOtherComprehensiveIncome" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Income Tax Charge (Credit) Relating To Hyperinflation Adjustment Included In Other Comprehensive Income</link:label>
    <link:label id="lab_deo_IncomeTaxChargeCreditRelatingToHyperinflationAdjustmentIncludedInOtherComprehensiveIncome_documentation_en" xlink:label="lab_deo_IncomeTaxChargeCreditRelatingToHyperinflationAdjustmentIncludedInOtherComprehensiveIncome" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Income Tax Charge (Credit) Relating To Hyperinflation Adjustment Included In Other Comprehensive Income</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncomeTaxChargeCreditRelatingToHyperinflationAdjustmentIncludedInOtherComprehensiveIncome" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncomeTaxChargeCreditRelatingToHyperinflationAdjustmentIncludedInOtherComprehensiveIncome"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncomeTaxChargeCreditRelatingToHyperinflationAdjustmentIncludedInOtherComprehensiveIncome" xlink:to="lab_deo_IncomeTaxChargeCreditRelatingToHyperinflationAdjustmentIncludedInOtherComprehensiveIncome" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfStepAcquisitions_label_en" xlink:label="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfStepAcquisitions" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Exchange Gain (Loss) Recycled To The Income Statement On Translation Of Foreign Operations In Respect Of Step Acquisitions</link:label>
    <link:label id="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfStepAcquisitions_documentation_en" xlink:label="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfStepAcquisitions" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Exchange Gain (Loss) Recycled To The Income Statement On Translation Of Foreign Operations In Respect Of Step Acquisitions</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfStepAcquisitions" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfStepAcquisitions"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfStepAcquisitions" xlink:to="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementOnTranslationOfForeignOperationsInRespectOfStepAcquisitions" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_PurchaseOfSharesOfNonControllingInterests_label_en" xlink:label="lab_deo_PurchaseOfSharesOfNonControllingInterests" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Purchase Of Shares Of Non-Controlling Interests</link:label>
    <link:label id="lab_deo_PurchaseOfSharesOfNonControllingInterests_documentation_en" xlink:label="lab_deo_PurchaseOfSharesOfNonControllingInterests" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Purchase Of Shares Of Non-Controlling Interests</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_PurchaseOfSharesOfNonControllingInterests" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_PurchaseOfSharesOfNonControllingInterests"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_PurchaseOfSharesOfNonControllingInterests" xlink:to="lab_deo_PurchaseOfSharesOfNonControllingInterests" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_AdjustmentsForIncreaseDecreaseInTradeAndOtherPayablesAndProvisions_label_en" xlink:label="lab_deo_AdjustmentsForIncreaseDecreaseInTradeAndOtherPayablesAndProvisions" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Adjustments For Increase (Decrease) In Trade And Other Payables And Provisions</link:label>
    <link:label id="lab_deo_AdjustmentsForIncreaseDecreaseInTradeAndOtherPayablesAndProvisions_documentation_en" xlink:label="lab_deo_AdjustmentsForIncreaseDecreaseInTradeAndOtherPayablesAndProvisions" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Adjustments For Increase (Decrease) In Trade And Other Payables And Provisions</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_AdjustmentsForIncreaseDecreaseInTradeAndOtherPayablesAndProvisions" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_AdjustmentsForIncreaseDecreaseInTradeAndOtherPayablesAndProvisions"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_AdjustmentsForIncreaseDecreaseInTradeAndOtherPayablesAndProvisions" xlink:to="lab_deo_AdjustmentsForIncreaseDecreaseInTradeAndOtherPayablesAndProvisions" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_IncreaseDecreaseThroughUnclaimedDividendsEquity_label_en" xlink:label="lab_deo_IncreaseDecreaseThroughUnclaimedDividendsEquity" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Unclaimed Dividends, Equity</link:label>
    <link:label id="lab_deo_IncreaseDecreaseThroughUnclaimedDividendsEquity_documentation_en" xlink:label="lab_deo_IncreaseDecreaseThroughUnclaimedDividendsEquity" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Increase (Decrease) Through Unclaimed Dividends, Equity</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_IncreaseDecreaseThroughUnclaimedDividendsEquity" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_IncreaseDecreaseThroughUnclaimedDividendsEquity"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_IncreaseDecreaseThroughUnclaimedDividendsEquity" xlink:to="lab_deo_IncreaseDecreaseThroughUnclaimedDividendsEquity" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCommodityPriceRiskHedging_label_en" xlink:label="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCommodityPriceRiskHedging" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Reclassification Adjustments On Cash Flow Hedges, Before Tax, Commodity Price Risk Hedging</link:label>
    <link:label id="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCommodityPriceRiskHedging_documentation_en" xlink:label="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCommodityPriceRiskHedging" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Reclassification Adjustments On Cash Flow Hedges, Before Tax, Commodity Price Risk Hedging</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCommodityPriceRiskHedging" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCommodityPriceRiskHedging"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCommodityPriceRiskHedging" xlink:to="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxCommodityPriceRiskHedging" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_PaymentsToAcquireOrRedeemTreasurySharesInRespectOfSubsidiaries_label_en" xlink:label="lab_deo_PaymentsToAcquireOrRedeemTreasurySharesInRespectOfSubsidiaries" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Payments To Acquire Or Redeem Treasury Shares In Respect Of Subsidiaries</link:label>
    <link:label id="lab_deo_PaymentsToAcquireOrRedeemTreasurySharesInRespectOfSubsidiaries_documentation_en" xlink:label="lab_deo_PaymentsToAcquireOrRedeemTreasurySharesInRespectOfSubsidiaries" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Payments To Acquire Or Redeem Treasury Shares In Respect Of Subsidiaries</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_PaymentsToAcquireOrRedeemTreasurySharesInRespectOfSubsidiaries" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_PaymentsToAcquireOrRedeemTreasurySharesInRespectOfSubsidiaries"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_PaymentsToAcquireOrRedeemTreasurySharesInRespectOfSubsidiaries" xlink:to="lab_deo_PaymentsToAcquireOrRedeemTreasurySharesInRespectOfSubsidiaries" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherRetainedEarningsMember_label_en" xlink:label="lab_deo_OtherRetainedEarningsMember" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Retained Earnings [Member]</link:label>
    <link:label id="lab_deo_OtherRetainedEarningsMember_documentation_en" xlink:label="lab_deo_OtherRetainedEarningsMember" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Retained Earnings [Member]</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherRetainedEarningsMember" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherRetainedEarningsMember"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherRetainedEarningsMember" xlink:to="lab_deo_OtherRetainedEarningsMember" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsNoncontrollingInterest_label_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsNoncontrollingInterest" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Exchange Differences On Translation Of Foreign Operations, Noncontrolling Interest</link:label>
    <link:label id="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsNoncontrollingInterest_documentation_en" xlink:label="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsNoncontrollingInterest" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income, Before Tax, Exchange Differences On Translation Of Foreign Operations, Noncontrolling Interest</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsNoncontrollingInterest" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsNoncontrollingInterest"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsNoncontrollingInterest" xlink:to="lab_deo_OtherComprehensiveIncomeBeforeTaxExchangeDifferencesOnTranslationOfForeignOperationsNoncontrollingInterest" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxHedgeOfForeignCurrencyDebt_label_en" xlink:label="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxHedgeOfForeignCurrencyDebt" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Reclassification Adjustments On Cash Flow Hedges, Before Tax, Hedge Of Foreign Currency Debt</link:label>
    <link:label id="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxHedgeOfForeignCurrencyDebt_documentation_en" xlink:label="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxHedgeOfForeignCurrencyDebt" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Reclassification Adjustments On Cash Flow Hedges, Before Tax, Hedge Of Foreign Currency Debt</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxHedgeOfForeignCurrencyDebt" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxHedgeOfForeignCurrencyDebt"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxHedgeOfForeignCurrencyDebt" xlink:to="lab_deo_ReclassificationAdjustmentsOnCashFlowHedgesBeforeTaxHedgeOfForeignCurrencyDebt" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_AdjustedWeightedAverageShares_692798c9-175e-4dd6-9e25-611ea0b3467b_totalLabel_en" xlink:label="lab_ifrs-full_AdjustedWeightedAverageShares" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Adjusted weighted average number of ordinary shares outstanding</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_AdjustedWeightedAverageShares" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_AdjustedWeightedAverageShares"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_AdjustedWeightedAverageShares" xlink:to="lab_ifrs-full_AdjustedWeightedAverageShares" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_SaleOfBusinessesAndBrands_label_en" xlink:label="lab_deo_SaleOfBusinessesAndBrands" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Sale Of Businesses And Brands</link:label>
    <link:label id="lab_deo_SaleOfBusinessesAndBrands_documentation_en" xlink:label="lab_deo_SaleOfBusinessesAndBrands" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Sale Of Businesses And Brands</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_SaleOfBusinessesAndBrands" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_SaleOfBusinessesAndBrands"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_SaleOfBusinessesAndBrands" xlink:to="lab_deo_SaleOfBusinessesAndBrands" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementAbstract_label_en" xlink:label="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementAbstract" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Exchange Gain (Loss) Recycled To The Income Statement [Abstract]</link:label>
    <link:label id="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementAbstract_documentation_en" xlink:label="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementAbstract" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Exchange Gain (Loss) Recycled To The Income Statement</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ExchangeGainLossRecycledToTheIncomeStatementAbstract" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ExchangeGainLossRecycledToTheIncomeStatementAbstract"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ExchangeGainLossRecycledToTheIncomeStatementAbstract" xlink:to="lab_deo_ExchangeGainLossRecycledToTheIncomeStatementAbstract" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_CashFlowsFromUsedInOperations_4dca384a-55ef-49bb-aa5e-7c7a235ab94a_totalLabel_en" xlink:label="lab_ifrs-full_CashFlowsFromUsedInOperations" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Cash flows from (used in) operations</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_CashFlowsFromUsedInOperations" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_CashFlowsFromUsedInOperations"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_CashFlowsFromUsedInOperations" xlink:to="lab_ifrs-full_CashFlowsFromUsedInOperations" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_ExciseDuties_label_en" xlink:label="lab_deo_ExciseDuties" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Excise Duties</link:label>
    <link:label id="lab_deo_ExciseDuties_documentation_en" xlink:label="lab_deo_ExciseDuties" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Excise Duties</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_ExciseDuties" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_ExciseDuties"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_ExciseDuties" xlink:to="lab_deo_ExciseDuties" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_PaymentsToAcquireOrRedeemEntitysSharesShareBuybackProgramme_label_en" xlink:label="lab_deo_PaymentsToAcquireOrRedeemEntitysSharesShareBuybackProgramme" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Payments To Acquire Or Redeem Entitys Shares Share Buyback Programme</link:label>
    <link:label id="lab_deo_PaymentsToAcquireOrRedeemEntitysSharesShareBuybackProgramme_documentation_en" xlink:label="lab_deo_PaymentsToAcquireOrRedeemEntitysSharesShareBuybackProgramme" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Payments To Acquire Or Redeem Entitys Shares Share Buyback Programme</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_PaymentsToAcquireOrRedeemEntitysSharesShareBuybackProgramme" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_PaymentsToAcquireOrRedeemEntitysSharesShareBuybackProgramme"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_PaymentsToAcquireOrRedeemEntitysSharesShareBuybackProgramme" xlink:to="lab_deo_PaymentsToAcquireOrRedeemEntitysSharesShareBuybackProgramme" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_NetAssetsLiabilities_36e0b169-f642-471a-854d-aee86aaf23c1_totalLabel_en" xlink:label="lab_ifrs-full_NetAssetsLiabilities" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Assets (liabilities)</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_NetAssetsLiabilities" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_NetAssetsLiabilities"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_NetAssetsLiabilities" xlink:to="lab_ifrs-full_NetAssetsLiabilities" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_PurchaseOfPropertyPlantAndEquipmentAndComputerSoftware_label_en" xlink:label="lab_deo_PurchaseOfPropertyPlantAndEquipmentAndComputerSoftware" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Purchase Of Property, Plant And Equipment And Computer Software</link:label>
    <link:label id="lab_deo_PurchaseOfPropertyPlantAndEquipmentAndComputerSoftware_documentation_en" xlink:label="lab_deo_PurchaseOfPropertyPlantAndEquipmentAndComputerSoftware" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Purchase Of Property, Plant And Equipment And Computer Software</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_PurchaseOfPropertyPlantAndEquipmentAndComputerSoftware" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_PurchaseOfPropertyPlantAndEquipmentAndComputerSoftware"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_PurchaseOfPropertyPlantAndEquipmentAndComputerSoftware" xlink:to="lab_deo_PurchaseOfPropertyPlantAndEquipmentAndComputerSoftware" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_IncreaseDecreaseInCashAndCashEquivalentsBeforeEffectOfExchangeRateChanges_b4ae6b8f-a1d2-46af-9c48-96a6cb192fc8_totalLabel_en" xlink:label="lab_ifrs-full_IncreaseDecreaseInCashAndCashEquivalentsBeforeEffectOfExchangeRateChanges" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Increase (decrease) in cash and cash equivalents before effect of exchange rate changes</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_IncreaseDecreaseInCashAndCashEquivalentsBeforeEffectOfExchangeRateChanges" xlink:href="https://xbrl.ifrs.org/taxonomy/2022-03-24/full_ifrs/full_ifrs-cor_2022-03-24.xsd#ifrs-full_IncreaseDecreaseInCashAndCashEquivalentsBeforeEffectOfExchangeRateChanges"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_IncreaseDecreaseInCashAndCashEquivalentsBeforeEffectOfExchangeRateChanges" xlink:to="lab_ifrs-full_IncreaseDecreaseInCashAndCashEquivalentsBeforeEffectOfExchangeRateChanges" xlink:type="arc" order="1"/>
    <link:label id="lab_deo_HyperinflationGainLossesRecognisedInOtherComprehensiveIncomeBeforeTax_label_en" xlink:label="lab_deo_HyperinflationGainLossesRecognisedInOtherComprehensiveIncomeBeforeTax" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Hyperinflation, Gain (Losses) Recognised In Other Comprehensive Income, Before Tax</link:label>
    <link:label id="lab_deo_HyperinflationGainLossesRecognisedInOtherComprehensiveIncomeBeforeTax_documentation_en" xlink:label="lab_deo_HyperinflationGainLossesRecognisedInOtherComprehensiveIncomeBeforeTax" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Hyperinflation, Gain (Losses) Recognised In Other Comprehensive Income, Before Tax</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_deo_HyperinflationGainLossesRecognisedInOtherComprehensiveIncomeBeforeTax" xlink:href="213800ZVIELEA55JMJ32-2024-06-30.xsd#deo_HyperinflationGainLossesRecognisedInOtherComprehensiveIncomeBeforeTax"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_deo_HyperinflationGainLossesRecognisedInOtherComprehensiveIncomeBeforeTax" xlink:to="lab_deo_HyperinflationGainLossesRecognisedInOtherComprehensiveIncomeBeforeTax" xlink:type="arc" order="1"/>
  </link:labelLink>
</link:linkbase>
