<?xml version="1.0" encoding="UTF-8"?>

<!--XBRL Document Created with the Workiva Platform-->
<!--Copyright 2026 Workiva-->
<!--r:7b67ecea-7a11-437c-9b35-45a02d707441,g:43f52e09-172d-434f-ae5a-0142a79ac805-->
<link:linkbase xmlns:link="http://www.xbrl.org/2003/linkbase" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.xbrl.org/2003/linkbase http://www.xbrl.org/2003/xbrl-linkbase-2003-12-31.xsd">
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedPeriodStartLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedPeriodStartLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/netLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/net-2009-12-16.xsd#netLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedNetLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedNetLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedTerseLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedTerseLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedPeriodEndLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedPeriodEndLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedLabel"/>
  <link:roleRef roleURI="http://www.xbrl.org/2009/role/negatedTotalLabel" xlink:type="simple" xlink:href="http://www.xbrl.org/lrr/role/negated-2009-12-16.xsd#negatedTotalLabel"/>
  <link:labelLink xlink:role="http://www.xbrl.org/2003/role/link" xlink:type="extended">
    <link:label id="lab_riotintoplc_ExchangeGainsLossesOnUsDollarExternalDebtAndIntraGroup_label_en" xlink:label="lab_riotintoplc_ExchangeGainsLossesOnUsDollarExternalDebtAndIntraGroup" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Exchange Gains (Losses) On Us Dollar External Debt And Intra Group</link:label>
    <link:label id="lab_riotintoplc_ExchangeGainsLossesOnUsDollarExternalDebtAndIntraGroup_documentation_en" xlink:label="lab_riotintoplc_ExchangeGainsLossesOnUsDollarExternalDebtAndIntraGroup" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Exchange Gains (Losses) On Us Dollar External Debt And Intra Group</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_ExchangeGainsLossesOnUsDollarExternalDebtAndIntraGroup" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_ExchangeGainsLossesOnUsDollarExternalDebtAndIntraGroup"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_ExchangeGainsLossesOnUsDollarExternalDebtAndIntraGroup" xlink:to="lab_riotintoplc_ExchangeGainsLossesOnUsDollarExternalDebtAndIntraGroup" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_UtilisationOfProvisionsForOtherProvisionsIncludingOnerousContractsAndLegalDisputes_label_en" xlink:label="lab_riotintoplc_UtilisationOfProvisionsForOtherProvisionsIncludingOnerousContractsAndLegalDisputes" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Utilisation Of Provisions For Other Provisions (Including Onerous Contracts And Legal Disputes)</link:label>
    <link:label id="lab_riotintoplc_UtilisationOfProvisionsForOtherProvisionsIncludingOnerousContractsAndLegalDisputes_documentation_en" xlink:label="lab_riotintoplc_UtilisationOfProvisionsForOtherProvisionsIncludingOnerousContractsAndLegalDisputes" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Utilisation Of Provisions For Other Provisions (Including Onerous Contracts And Legal Disputes)</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_UtilisationOfProvisionsForOtherProvisionsIncludingOnerousContractsAndLegalDisputes" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_UtilisationOfProvisionsForOtherProvisionsIncludingOnerousContractsAndLegalDisputes"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_UtilisationOfProvisionsForOtherProvisionsIncludingOnerousContractsAndLegalDisputes" xlink:to="lab_riotintoplc_UtilisationOfProvisionsForOtherProvisionsIncludingOnerousContractsAndLegalDisputes" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_NotDesignatedAsHedgingInstrumentMember_label_en" xlink:label="lab_riotintoplc_NotDesignatedAsHedgingInstrumentMember" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Not Designated As Hedging Instrument [Member]</link:label>
    <link:label id="lab_riotintoplc_NotDesignatedAsHedgingInstrumentMember_documentation_en" xlink:label="lab_riotintoplc_NotDesignatedAsHedgingInstrumentMember" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Not Designated As Hedging Instrument</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_NotDesignatedAsHedgingInstrumentMember" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_NotDesignatedAsHedgingInstrumentMember"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_NotDesignatedAsHedgingInstrumentMember" xlink:to="lab_riotintoplc_NotDesignatedAsHedgingInstrumentMember" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_OtherComprehensiveIncomeBeforeTaxCostsOfHedging_label_en" xlink:label="lab_riotintoplc_OtherComprehensiveIncomeBeforeTaxCostsOfHedging" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other Comprehensive Income Before Tax Costs Of Hedging</link:label>
    <link:label id="lab_riotintoplc_OtherComprehensiveIncomeBeforeTaxCostsOfHedging_documentation_en" xlink:label="lab_riotintoplc_OtherComprehensiveIncomeBeforeTaxCostsOfHedging" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Other Comprehensive Income Before Tax Costs Of Hedging</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_OtherComprehensiveIncomeBeforeTaxCostsOfHedging" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_OtherComprehensiveIncomeBeforeTaxCostsOfHedging"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_OtherComprehensiveIncomeBeforeTaxCostsOfHedging" xlink:to="lab_riotintoplc_OtherComprehensiveIncomeBeforeTaxCostsOfHedging" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_TotalNetOutflowsInIronOreProject_019be743-7369-7f5e-a33d-ad1ed6edc020_terseLabel_en" xlink:label="lab_riotintoplc_TotalNetOutflowsInIronOreProject" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xlink:type="resource" xml:lang="en">Total Net Outflows In Iron Ore Project</link:label>
    <link:label id="lab_riotintoplc_TotalNetOutflowsInIronOreProject_label_en" xlink:label="lab_riotintoplc_TotalNetOutflowsInIronOreProject" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Total Net Outflows In Iron Ore Project</link:label>
    <link:label id="lab_riotintoplc_TotalNetOutflowsInIronOreProject_documentation_en" xlink:label="lab_riotintoplc_TotalNetOutflowsInIronOreProject" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Total Net Outflows In Iron Ore Project</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_TotalNetOutflowsInIronOreProject" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_TotalNetOutflowsInIronOreProject"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_TotalNetOutflowsInIronOreProject" xlink:to="lab_riotintoplc_TotalNetOutflowsInIronOreProject" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_CurrencyTranslationGainChargeArisingOnDualListedCompaniesShareCapital_label_en" xlink:label="lab_riotintoplc_CurrencyTranslationGainChargeArisingOnDualListedCompaniesShareCapital" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Currency Translation Gain (Charge) Arising On Dual Listed Companies Share Capital</link:label>
    <link:label id="lab_riotintoplc_CurrencyTranslationGainChargeArisingOnDualListedCompaniesShareCapital_documentation_en" xlink:label="lab_riotintoplc_CurrencyTranslationGainChargeArisingOnDualListedCompaniesShareCapital" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Currency Translation Gain (Charge) Arising On Dual Listed Companies Share Capital</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_CurrencyTranslationGainChargeArisingOnDualListedCompaniesShareCapital" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_CurrencyTranslationGainChargeArisingOnDualListedCompaniesShareCapital"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_CurrencyTranslationGainChargeArisingOnDualListedCompaniesShareCapital" xlink:to="lab_riotintoplc_CurrencyTranslationGainChargeArisingOnDualListedCompaniesShareCapital" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_AdjustmentsForGainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation_label_en" xlink:label="lab_riotintoplc_AdjustmentsForGainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Adjustments For Gain (Loss) Recognised On Measurement To Fair Value Of Business Combination And Disposal Disposal Of Assets Or Disposal Groups Constituting Discontinued Operation</link:label>
    <link:label id="lab_riotintoplc_AdjustmentsForGainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation_documentation_en" xlink:label="lab_riotintoplc_AdjustmentsForGainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Adjustments For Gain (Loss) Recognised On Measurement To Fair Value Of Business Combination And Disposal Disposal Of Assets Or Disposal Groups Constituting Discontinued Operation</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_AdjustmentsForGainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_AdjustmentsForGainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_AdjustmentsForGainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation" xlink:to="lab_riotintoplc_AdjustmentsForGainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_AdjustmentsForFinanceIncomeCost_bb741700-a895-42fa-bed9-2753731baa34_terseLabel_en" xlink:label="lab_ifrs-full_AdjustmentsForFinanceIncomeCost" xlink:role="http://www.xbrl.org/2003/role/terseLabel" xlink:type="resource" xml:lang="en">Adjustments for finance income (cost)</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_AdjustmentsForFinanceIncomeCost" xlink:href="https://xbrl.ifrs.org/taxonomy/2024-03-27/full_ifrs/full_ifrs-cor_2024-03-27.xsd#ifrs-full_AdjustmentsForFinanceIncomeCost"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_AdjustmentsForFinanceIncomeCost" xlink:to="lab_ifrs-full_AdjustmentsForFinanceIncomeCost" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_CashFlowsUsedInObtainingEquityAccountedUnit_label_en" xlink:label="lab_riotintoplc_CashFlowsUsedInObtainingEquityAccountedUnit" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Cash Flows Used In Obtaining Equity Accounted Unit</link:label>
    <link:label id="lab_riotintoplc_CashFlowsUsedInObtainingEquityAccountedUnit_documentation_en" xlink:label="lab_riotintoplc_CashFlowsUsedInObtainingEquityAccountedUnit" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Cash Flows Used In Obtaining Equity Accounted Unit</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_CashFlowsUsedInObtainingEquityAccountedUnit" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_CashFlowsUsedInObtainingEquityAccountedUnit"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_CashFlowsUsedInObtainingEquityAccountedUnit" xlink:to="lab_riotintoplc_CashFlowsUsedInObtainingEquityAccountedUnit" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_SimandouIronOreProjectMember_label_en" xlink:label="lab_riotintoplc_SimandouIronOreProjectMember" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Simandou Iron Ore Project [Member]</link:label>
    <link:label id="lab_riotintoplc_SimandouIronOreProjectMember_documentation_en" xlink:label="lab_riotintoplc_SimandouIronOreProjectMember" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Simandou Iron Ore Project</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_SimandouIronOreProjectMember" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_SimandouIronOreProjectMember"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_SimandouIronOreProjectMember" xlink:to="lab_riotintoplc_SimandouIronOreProjectMember" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_UtilisationOfProvisionsForPostRetirementBenefitsAndOtherEmploymentCosts_label_en" xlink:label="lab_riotintoplc_UtilisationOfProvisionsForPostRetirementBenefitsAndOtherEmploymentCosts" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Utilisation Of Provisions For Post-Retirement Benefits And Other Employment Costs</link:label>
    <link:label id="lab_riotintoplc_UtilisationOfProvisionsForPostRetirementBenefitsAndOtherEmploymentCosts_documentation_en" xlink:label="lab_riotintoplc_UtilisationOfProvisionsForPostRetirementBenefitsAndOtherEmploymentCosts" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Utilisation Of Provisions For Post-Retirement Benefits And Other Employment Costs</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_UtilisationOfProvisionsForPostRetirementBenefitsAndOtherEmploymentCosts" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_UtilisationOfProvisionsForPostRetirementBenefitsAndOtherEmploymentCosts"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_UtilisationOfProvisionsForPostRetirementBenefitsAndOtherEmploymentCosts" xlink:to="lab_riotintoplc_UtilisationOfProvisionsForPostRetirementBenefitsAndOtherEmploymentCosts" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_CashFlowsFromUsedInFinancingActivities_6756868e-dd7e-4175-be97-192f0f276900_totalLabel_en" xlink:label="lab_ifrs-full_CashFlowsFromUsedInFinancingActivities" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Cash flows from (used in) financing activities</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_CashFlowsFromUsedInFinancingActivities" xlink:href="https://xbrl.ifrs.org/taxonomy/2024-03-27/full_ifrs/full_ifrs-cor_2024-03-27.xsd#ifrs-full_CashFlowsFromUsedInFinancingActivities"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_CashFlowsFromUsedInFinancingActivities" xlink:to="lab_ifrs-full_CashFlowsFromUsedInFinancingActivities" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_GainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation_label_en" xlink:label="lab_riotintoplc_GainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Gain (Loss) Recognised On Measurement To Fair Value Of Business Combination And Disposal Disposal Of Assets Or Disposal Groups Constituting Discontinued Operation</link:label>
    <link:label id="lab_riotintoplc_GainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation_documentation_en" xlink:label="lab_riotintoplc_GainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Gain (Loss) Recognised On Measurement To Fair Value Of Business Combination And Disposal Disposal Of Assets Or Disposal Groups Constituting Discontinued Operation</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_GainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_GainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_GainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation" xlink:to="lab_riotintoplc_GainLossRecognisedOnMeasurementToFairValueOfBusinessCombinationAndDisposalDisposalOfAssetsOrDisposalGroupsConstitutingDiscontinuedOperation" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_CashFlowsFromUsedInConsolidatedOperations_label_en" xlink:label="lab_riotintoplc_CashFlowsFromUsedInConsolidatedOperations" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Cash Flows From Used In Consolidated Operations</link:label>
    <link:label id="lab_riotintoplc_CashFlowsFromUsedInConsolidatedOperations_documentation_en" xlink:label="lab_riotintoplc_CashFlowsFromUsedInConsolidatedOperations" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Cash Flows From Used In Consolidated Operations</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_CashFlowsFromUsedInConsolidatedOperations" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_CashFlowsFromUsedInConsolidatedOperations"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_CashFlowsFromUsedInConsolidatedOperations" xlink:to="lab_riotintoplc_CashFlowsFromUsedInConsolidatedOperations" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_CashFlowsFromUsedInInvestingActivities_6bcd5e7d-ca29-4386-904c-8b2ed9c3dd79_totalLabel_en" xlink:label="lab_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Cash flows from (used in) investing activities</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:href="https://xbrl.ifrs.org/taxonomy/2024-03-27/full_ifrs/full_ifrs-cor_2024-03-27.xsd#ifrs-full_CashFlowsFromUsedInInvestingActivities"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:to="lab_ifrs-full_CashFlowsFromUsedInInvestingActivities" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_DescriptionOfAccountingPolicyForImpactOfClimateChangeOnTheGroupTextBlock_label_en" xlink:label="lab_riotintoplc_DescriptionOfAccountingPolicyForImpactOfClimateChangeOnTheGroupTextBlock" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Description Of Accounting Policy For Impact Of Climate Change On The Group [Text Block]</link:label>
    <link:label id="lab_riotintoplc_DescriptionOfAccountingPolicyForImpactOfClimateChangeOnTheGroupTextBlock_documentation_en" xlink:label="lab_riotintoplc_DescriptionOfAccountingPolicyForImpactOfClimateChangeOnTheGroupTextBlock" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Description Of Accounting Policy For Impact Of Climate Change On The Group</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_DescriptionOfAccountingPolicyForImpactOfClimateChangeOnTheGroupTextBlock" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_DescriptionOfAccountingPolicyForImpactOfClimateChangeOnTheGroupTextBlock"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_DescriptionOfAccountingPolicyForImpactOfClimateChangeOnTheGroupTextBlock" xlink:to="lab_riotintoplc_DescriptionOfAccountingPolicyForImpactOfClimateChangeOnTheGroupTextBlock" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_CurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts_label_en" xlink:label="lab_riotintoplc_CurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Current Provisions For Employee Benefits And Other Employment Costs</link:label>
    <link:label id="lab_riotintoplc_CurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts_documentation_en" xlink:label="lab_riotintoplc_CurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Current Provisions For Employee Benefits And Other Employment Costs</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_CurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_CurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_CurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" xlink:to="lab_riotintoplc_CurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_DisclosureOfCloseDownRestorationAndEnvironmentalObligationsTextBlock_label_en" xlink:label="lab_riotintoplc_DisclosureOfCloseDownRestorationAndEnvironmentalObligationsTextBlock" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Disclosure Of Close-Down, Restoration And Environmental Obligations [Text Block]</link:label>
    <link:label id="lab_riotintoplc_DisclosureOfCloseDownRestorationAndEnvironmentalObligationsTextBlock_documentation_en" xlink:label="lab_riotintoplc_DisclosureOfCloseDownRestorationAndEnvironmentalObligationsTextBlock" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Disclosure Of Close-Down, Restoration And Environmental Obligations</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_DisclosureOfCloseDownRestorationAndEnvironmentalObligationsTextBlock" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_DisclosureOfCloseDownRestorationAndEnvironmentalObligationsTextBlock"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_DisclosureOfCloseDownRestorationAndEnvironmentalObligationsTextBlock" xlink:to="lab_riotintoplc_DisclosureOfCloseDownRestorationAndEnvironmentalObligationsTextBlock" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_CashFlowsFromUsedInOperatingActivities_84664043-ffc2-4f4a-a217-329ac0a0b038_totalLabel_en" xlink:label="lab_ifrs-full_CashFlowsFromUsedInOperatingActivities" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Cash flows from (used in) operating activities</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_CashFlowsFromUsedInOperatingActivities" xlink:href="https://xbrl.ifrs.org/taxonomy/2024-03-27/full_ifrs/full_ifrs-cor_2024-03-27.xsd#ifrs-full_CashFlowsFromUsedInOperatingActivities"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_CashFlowsFromUsedInOperatingActivities" xlink:to="lab_ifrs-full_CashFlowsFromUsedInOperatingActivities" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_NonCurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts_label_en" xlink:label="lab_riotintoplc_NonCurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Non-Current Provisions For Employee Benefits And Other Employment Costs</link:label>
    <link:label id="lab_riotintoplc_NonCurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts_documentation_en" xlink:label="lab_riotintoplc_NonCurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Non-Current Provisions For Employee Benefits And Other Employment Costs</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_NonCurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_NonCurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_NonCurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" xlink:to="lab_riotintoplc_NonCurrentProvisionsForEmployeeBenefitsAndOtherEmploymentCosts" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_ChangeInFairValueOfEquityInvestmentsAtFairValueThroughOtherComprehensiveIncome_label_en" xlink:label="lab_riotintoplc_ChangeInFairValueOfEquityInvestmentsAtFairValueThroughOtherComprehensiveIncome" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Change In Fair Value Of Equity Investments At Fair Value Through Other Comprehensive Income</link:label>
    <link:label id="lab_riotintoplc_ChangeInFairValueOfEquityInvestmentsAtFairValueThroughOtherComprehensiveIncome_documentation_en" xlink:label="lab_riotintoplc_ChangeInFairValueOfEquityInvestmentsAtFairValueThroughOtherComprehensiveIncome" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Change In Fair Value Of Equity Investments At Fair Value Through Other Comprehensive Income</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_ChangeInFairValueOfEquityInvestmentsAtFairValueThroughOtherComprehensiveIncome" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_ChangeInFairValueOfEquityInvestmentsAtFairValueThroughOtherComprehensiveIncome"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_ChangeInFairValueOfEquityInvestmentsAtFairValueThroughOtherComprehensiveIncome" xlink:to="lab_riotintoplc_ChangeInFairValueOfEquityInvestmentsAtFairValueThroughOtherComprehensiveIncome" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_FinanceIncomeCost_cccdbca8-1388-4802-983e-bfe748cb89d5_totalLabel_en" xlink:label="lab_ifrs-full_FinanceIncomeCost" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Finance income (cost)</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_FinanceIncomeCost" xlink:href="https://xbrl.ifrs.org/taxonomy/2024-03-27/full_ifrs/full_ifrs-cor_2024-03-27.xsd#ifrs-full_FinanceIncomeCost"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_FinanceIncomeCost" xlink:to="lab_ifrs-full_FinanceIncomeCost" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_NetOperatingExpenses_label_en" xlink:label="lab_riotintoplc_NetOperatingExpenses" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Net Operating Expenses</link:label>
    <link:label id="lab_riotintoplc_NetOperatingExpenses_documentation_en" xlink:label="lab_riotintoplc_NetOperatingExpenses" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Net Operating Expenses</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_NetOperatingExpenses" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_NetOperatingExpenses"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_NetOperatingExpenses" xlink:to="lab_riotintoplc_NetOperatingExpenses" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_IncreaseDecreaseInCashAndCashEquivalents_da9140d2-d73a-46ce-bc05-95650561d4e7_totalLabel_en" xlink:label="lab_ifrs-full_IncreaseDecreaseInCashAndCashEquivalents" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Increase (decrease) in cash and cash equivalents after effect of exchange rate changes</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_IncreaseDecreaseInCashAndCashEquivalents" xlink:href="https://xbrl.ifrs.org/taxonomy/2024-03-27/full_ifrs/full_ifrs-cor_2024-03-27.xsd#ifrs-full_IncreaseDecreaseInCashAndCashEquivalents"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_IncreaseDecreaseInCashAndCashEquivalents" xlink:to="lab_ifrs-full_IncreaseDecreaseInCashAndCashEquivalents" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_CashFlowsBeforeFinancingActivities1_7ffd59ec-d57f-4158-86d0-03c6ca1fd045_totalLabel_en" xlink:label="lab_riotintoplc_CashFlowsBeforeFinancingActivities1" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Cash flows before financing activities1</link:label>
    <link:label id="lab_riotintoplc_CashFlowsBeforeFinancingActivities1_label_en" xlink:label="lab_riotintoplc_CashFlowsBeforeFinancingActivities1" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Cash flows before financing activities1</link:label>
    <link:label id="lab_riotintoplc_CashFlowsBeforeFinancingActivities1_documentation_en" xlink:label="lab_riotintoplc_CashFlowsBeforeFinancingActivities1" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Cash flows before financing activities1</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_CashFlowsBeforeFinancingActivities1" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_CashFlowsBeforeFinancingActivities1"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_CashFlowsBeforeFinancingActivities1" xlink:to="lab_riotintoplc_CashFlowsBeforeFinancingActivities1" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_DescriptionOfAccountingPolicyOfReconciliationWithAustralianAccountingStandardsTextBlock_label_en" xlink:label="lab_riotintoplc_DescriptionOfAccountingPolicyOfReconciliationWithAustralianAccountingStandardsTextBlock" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Description Of Accounting Policy Of Reconciliation With Australian Accounting Standards [Text Block]</link:label>
    <link:label id="lab_riotintoplc_DescriptionOfAccountingPolicyOfReconciliationWithAustralianAccountingStandardsTextBlock_documentation_en" xlink:label="lab_riotintoplc_DescriptionOfAccountingPolicyOfReconciliationWithAustralianAccountingStandardsTextBlock" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Description Of Accounting Policy Of Reconciliation With Australian Accounting Standards</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_DescriptionOfAccountingPolicyOfReconciliationWithAustralianAccountingStandardsTextBlock" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_DescriptionOfAccountingPolicyOfReconciliationWithAustralianAccountingStandardsTextBlock"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_DescriptionOfAccountingPolicyOfReconciliationWithAustralianAccountingStandardsTextBlock" xlink:to="lab_riotintoplc_DescriptionOfAccountingPolicyOfReconciliationWithAustralianAccountingStandardsTextBlock" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_CondensedCashFlowStatementTable_label_en" xlink:label="lab_riotintoplc_CondensedCashFlowStatementTable" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Condensed Cash Flow Statement [Table]</link:label>
    <link:label id="lab_riotintoplc_CondensedCashFlowStatementTable_documentation_en" xlink:label="lab_riotintoplc_CondensedCashFlowStatementTable" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Condensed Cash Flow Statement [Table]</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_CondensedCashFlowStatementTable" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_CondensedCashFlowStatementTable"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_CondensedCashFlowStatementTable" xlink:to="lab_riotintoplc_CondensedCashFlowStatementTable" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_FixedIncomeInstrumentsMember_label_en" xlink:label="lab_riotintoplc_FixedIncomeInstrumentsMember" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Fixed Income Instruments [Member]</link:label>
    <link:label id="lab_riotintoplc_FixedIncomeInstrumentsMember_documentation_en" xlink:label="lab_riotintoplc_FixedIncomeInstrumentsMember" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Fixed Income Instruments</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_FixedIncomeInstrumentsMember" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_FixedIncomeInstrumentsMember"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_FixedIncomeInstrumentsMember" xlink:to="lab_riotintoplc_FixedIncomeInstrumentsMember" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_ExpenseDueToUnwindingOfDiscountOnProvisionsAndReceivables_label_en" xlink:label="lab_riotintoplc_ExpenseDueToUnwindingOfDiscountOnProvisionsAndReceivables" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Expense Due To Unwinding Of Discount On Provisions And Receivables</link:label>
    <link:label id="lab_riotintoplc_ExpenseDueToUnwindingOfDiscountOnProvisionsAndReceivables_documentation_en" xlink:label="lab_riotintoplc_ExpenseDueToUnwindingOfDiscountOnProvisionsAndReceivables" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Expense Due To Unwinding Of Discount On Provisions And Receivables</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_ExpenseDueToUnwindingOfDiscountOnProvisionsAndReceivables" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_ExpenseDueToUnwindingOfDiscountOnProvisionsAndReceivables"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_ExpenseDueToUnwindingOfDiscountOnProvisionsAndReceivables" xlink:to="lab_riotintoplc_ExpenseDueToUnwindingOfDiscountOnProvisionsAndReceivables" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_CashFlowsFromUsedInOperations_2801e240-9b9d-4dab-8ac4-aef686c241da_totalLabel_en" xlink:label="lab_ifrs-full_CashFlowsFromUsedInOperations" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Cash flows from (used in) operations</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_CashFlowsFromUsedInOperations" xlink:href="https://xbrl.ifrs.org/taxonomy/2024-03-27/full_ifrs/full_ifrs-cor_2024-03-27.xsd#ifrs-full_CashFlowsFromUsedInOperations"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_CashFlowsFromUsedInOperations" xlink:to="lab_ifrs-full_CashFlowsFromUsedInOperations" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_ShareCapitalRioTintoLimited_label_en" xlink:label="lab_riotintoplc_ShareCapitalRioTintoLimited" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Share Capital – Rio Tinto Limited</link:label>
    <link:label id="lab_riotintoplc_ShareCapitalRioTintoLimited_documentation_en" xlink:label="lab_riotintoplc_ShareCapitalRioTintoLimited" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Share Capital – Rio Tinto Limited</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_ShareCapitalRioTintoLimited" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_ShareCapitalRioTintoLimited"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_ShareCapitalRioTintoLimited" xlink:to="lab_riotintoplc_ShareCapitalRioTintoLimited" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_WinningConsortiumSimandouRailwayPte.LtdAndWinningConsortiumSimandouPortsPte.Ltd_label_en" xlink:label="lab_riotintoplc_WinningConsortiumSimandouRailwayPte.LtdAndWinningConsortiumSimandouPortsPte.Ltd" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Winning Consortium Simandou Railway Pte. Ltd and Winning Consortium Simandou Ports Pte. Ltd [Member]</link:label>
    <link:label id="lab_riotintoplc_WinningConsortiumSimandouRailwayPte.LtdAndWinningConsortiumSimandouPortsPte.Ltd_documentation_en" xlink:label="lab_riotintoplc_WinningConsortiumSimandouRailwayPte.LtdAndWinningConsortiumSimandouPortsPte.Ltd" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Winning Consortium Simandou Railway Pte. Ltd and Winning Consortium Simandou Ports Pte. Ltd</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_WinningConsortiumSimandouRailwayPte.LtdAndWinningConsortiumSimandouPortsPte.Ltd" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_WinningConsortiumSimandouRailwayPte.LtdAndWinningConsortiumSimandouPortsPte.Ltd"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_WinningConsortiumSimandouRailwayPte.LtdAndWinningConsortiumSimandouPortsPte.Ltd" xlink:to="lab_riotintoplc_WinningConsortiumSimandouRailwayPte.LtdAndWinningConsortiumSimandouPortsPte.Ltd" xlink:type="arc" order="1"/>
    <link:label id="lab_ifrs-full_NetAssetsLiabilities_8906ef14-777b-4f36-9938-6bed291be802_totalLabel_en" xlink:label="lab_ifrs-full_NetAssetsLiabilities" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Assets (liabilities)</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_ifrs-full_NetAssetsLiabilities" xlink:href="https://xbrl.ifrs.org/taxonomy/2024-03-27/full_ifrs/full_ifrs-cor_2024-03-27.xsd#ifrs-full_NetAssetsLiabilities"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_ifrs-full_NetAssetsLiabilities" xlink:to="lab_ifrs-full_NetAssetsLiabilities" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_ShareCapitalRioTintoPlc_label_en" xlink:label="lab_riotintoplc_ShareCapitalRioTintoPlc" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Share Capital – Rio Tinto plc</link:label>
    <link:label id="lab_riotintoplc_ShareCapitalRioTintoPlc_documentation_en" xlink:label="lab_riotintoplc_ShareCapitalRioTintoPlc" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Share Capital – Rio Tinto plc</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_ShareCapitalRioTintoPlc" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_ShareCapitalRioTintoPlc"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_ShareCapitalRioTintoPlc" xlink:to="lab_riotintoplc_ShareCapitalRioTintoPlc" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_UtilisationOfProvisionsForCloseDownAndRestoration_label_en" xlink:label="lab_riotintoplc_UtilisationOfProvisionsForCloseDownAndRestoration" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Utilisation Of Provisions For Close Down And Restoration</link:label>
    <link:label id="lab_riotintoplc_UtilisationOfProvisionsForCloseDownAndRestoration_documentation_en" xlink:label="lab_riotintoplc_UtilisationOfProvisionsForCloseDownAndRestoration" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Utilisation Of Provisions For Close Down And Restoration</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_UtilisationOfProvisionsForCloseDownAndRestoration" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_UtilisationOfProvisionsForCloseDownAndRestoration"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_UtilisationOfProvisionsForCloseDownAndRestoration" xlink:to="lab_riotintoplc_UtilisationOfProvisionsForCloseDownAndRestoration" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_ProfitBeforeFinanceItemsAndTaxation1_91f5545f-0e6a-42fc-9148-f909c8bc62d9_totalLabel_en" xlink:label="lab_riotintoplc_ProfitBeforeFinanceItemsAndTaxation1" xlink:role="http://www.xbrl.org/2003/role/totalLabel" xlink:type="resource" xml:lang="en">Profit before finance items and taxation1</link:label>
    <link:label id="lab_riotintoplc_ProfitBeforeFinanceItemsAndTaxation1_label_en" xlink:label="lab_riotintoplc_ProfitBeforeFinanceItemsAndTaxation1" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Profit before finance items and taxation1</link:label>
    <link:label id="lab_riotintoplc_ProfitBeforeFinanceItemsAndTaxation1_documentation_en" xlink:label="lab_riotintoplc_ProfitBeforeFinanceItemsAndTaxation1" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Profit before finance items and taxation1</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_ProfitBeforeFinanceItemsAndTaxation1" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_ProfitBeforeFinanceItemsAndTaxation1"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_ProfitBeforeFinanceItemsAndTaxation1" xlink:to="lab_riotintoplc_ProfitBeforeFinanceItemsAndTaxation1" xlink:type="arc" order="1"/>
    <link:label id="lab_riotintoplc_CondensedCashFlowStatementLineItems_label_en" xlink:label="lab_riotintoplc_CondensedCashFlowStatementLineItems" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Condensed Cash Flow Statement [Line Items]</link:label>
    <link:label id="lab_riotintoplc_CondensedCashFlowStatementLineItems_documentation_en" xlink:label="lab_riotintoplc_CondensedCashFlowStatementLineItems" xlink:role="http://www.xbrl.org/2003/role/documentation" xlink:type="resource" xml:lang="en">Condensed Cash Flow Statement [Line Items]</link:label>
    <link:loc xlink:type="locator" xlink:label="loc_riotintoplc_CondensedCashFlowStatementLineItems" xlink:href="213800YOEO5OQ72G2R82-2025-12-31.xsd#riotintoplc_CondensedCashFlowStatementLineItems"/>
    <link:labelArc xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" xlink:from="loc_riotintoplc_CondensedCashFlowStatementLineItems" xlink:to="lab_riotintoplc_CondensedCashFlowStatementLineItems" xlink:type="arc" order="1"/>
  </link:labelLink>
</link:linkbase>
