<?xml version="1.0" encoding="utf-8"?>
<linkbase xsi:schemaLocation="http://www.xbrl.org/2003/linkbase http://www.xbrl.org/2003/xbrl-linkbase-2003-12-31.xsd" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.xbrl.org/2003/linkbase">
  <labelLink xlink:role="http://www.xbrl.org/2003/role/link" xlink:type="extended" xmlns:xlink="http://www.w3.org/1999/xlink">
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_CurrentBorrowingsAndOtherFinancialLiabilities" xlink:label="riotintoplc_CurrentBorrowingsAndOtherFinancialLiabilities" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_NetProceedsFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio" xlink:label="riotintoplc_NetProceedsFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_ShareCapitalRioTintoLimited" xlink:label="riotintoplc_ShareCapitalRioTintoLimited" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_ProfitRelatingToInterestsInUndevelopedProjects" xlink:label="riotintoplc_ProfitRelatingToInterestsInUndevelopedProjects" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_PensionSettlement" xlink:label="riotintoplc_PensionSettlement" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_NetCashOutflowFromRepaymentOfBond" xlink:label="riotintoplc_NetCashOutflowFromRepaymentOfBond" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_CurrencyTranslationArisingOnRioTintoLimitedsShareCapital" xlink:label="riotintoplc_CurrencyTranslationArisingOnRioTintoLimitedsShareCapital" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_AdjustmentsForImpairmentChargesNetOfReversals" xlink:label="riotintoplc_AdjustmentsForImpairmentChargesNetOfReversals" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_ChangeInEquityInterestHeldByRioTinto" xlink:label="riotintoplc_ChangeInEquityInterestHeldByRioTinto" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_OwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareAwardsToEmployees" xlink:label="riotintoplc_OwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareAwardsToEmployees" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_NominalValueOfBondBuyBackProgramme" xlink:label="riotintoplc_NominalValueOfBondBuyBackProgramme" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_TotalAmountHeldInTrustFund" xlink:label="riotintoplc_TotalAmountHeldInTrustFund" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_TotalCashOutflowFromRepaymentOfBorrowings" xlink:label="riotintoplc_TotalCashOutflowFromRepaymentOfBorrowings" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_ImpairmentChargesNetOfReversals" xlink:label="riotintoplc_ImpairmentChargesNetOfReversals" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_ShareCapitalRioTintoPlc" xlink:label="riotintoplc_ShareCapitalRioTintoPlc" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_ShareBuyBack" xlink:label="riotintoplc_ShareBuyBack" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_AdjustmentsForProvisionsIncludingExchangeDifferencesOnProvisions" xlink:label="riotintoplc_AdjustmentsForProvisionsIncludingExchangeDifferencesOnProvisions" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_NetPurchaseFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio" xlink:label="riotintoplc_NetPurchaseFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_DebtSecuritiesIssued" xlink:label="riotintoplc_DebtSecuritiesIssued" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_OtherCashOutflowRelatingToPaymentsIntoTrustFund" xlink:label="riotintoplc_OtherCashOutflowRelatingToPaymentsIntoTrustFund" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_AdjustmentsForUtilisationOfProvisions" xlink:label="riotintoplc_AdjustmentsForUtilisationOfProvisions" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_AdjustmentsForImpairmentChargesOfInvestmentsInEquityAccountedUnitsAfterTax" xlink:label="riotintoplc_AdjustmentsForImpairmentChargesOfInvestmentsInEquityAccountedUnitsAfterTax" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_CashFlowsBeforeFinancingActivities" xlink:label="riotintoplc_CashFlowsBeforeFinancingActivities" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_NominalValueOfBondRepaid" xlink:label="riotintoplc_NominalValueOfBondRepaid" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_CompaniesNoLongerConsolidated" xlink:label="riotintoplc_CompaniesNoLongerConsolidated" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_OwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareOptions" xlink:label="riotintoplc_OwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareOptions" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_GainOnRecognitionIncludedInOtherItems" xlink:label="riotintoplc_GainOnRecognitionIncludedInOtherItems" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_NetChangeInCostsOfHedging" xlink:label="riotintoplc_NetChangeInCostsOfHedging" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_NoncurrentBorrowingsAndOtherFinancialLiabilities" xlink:label="riotintoplc_NoncurrentBorrowingsAndOtherFinancialLiabilities" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_ImpairmentOfInvestmentsInEquityAccountedUnits" xlink:label="riotintoplc_ImpairmentOfInvestmentsInEquityAccountedUnits" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_ProfitBeforeFinanceItemsAndTaxation" xlink:label="riotintoplc_ProfitBeforeFinanceItemsAndTaxation" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_CashFlowsFromConsolidatedOperations" xlink:label="riotintoplc_CashFlowsFromConsolidatedOperations" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_TaxPaymentRequired" xlink:label="riotintoplc_TaxPaymentRequired" />
    <loc xlink:type="locator" xlink:href="riotintoplc-2021-12-31.xsd#riotintoplc_CurrencyTranslationCharge" xlink:label="riotintoplc_CurrencyTranslationCharge" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_ImpairmentChargesNetOfReversals" xlink:to="label_riotintoplc_riotintoplcImpairmentChargesNetOfReversals_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_ProfitRelatingToInterestsInUndevelopedProjects" xlink:to="label_riotintoplc_riotintoplcProfitRelatingToInterestsInUndevelopedProjects_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_ImpairmentOfInvestmentsInEquityAccountedUnits" xlink:to="label_riotintoplc_riotintoplcImpairmentOfInvestmentsInEquityAccountedUnits_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_ProfitBeforeFinanceItemsAndTaxation" xlink:to="label_riotintoplc_riotintoplcProfitBeforeFinanceItemsAndTaxation_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_NetChangeInCostsOfHedging" xlink:to="label_riotintoplc_riotintoplcNetChangeInCostsOfHedging_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_CurrencyTranslationCharge" xlink:to="label_riotintoplc_riotintoplcCurrencyTranslationCharge_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_CashFlowsFromConsolidatedOperations" xlink:to="label_riotintoplc_riotintoplcCashFlowsFromConsolidatedOperations_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_CashFlowsBeforeFinancingActivities" xlink:to="label_riotintoplc_riotintoplcCashFlowsBeforeFinancingActivities_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_AdjustmentsForImpairmentChargesOfInvestmentsInEquityAccountedUnitsAfterTax" xlink:to="label_riotintoplc_riotintoplcAdjustmentsForImpairmentChargesOfInvestmentsInEquityAccountedUnitsAfterTax_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_AdjustmentsForImpairmentChargesNetOfReversals" xlink:to="label_riotintoplc_riotintoplcAdjustmentsForImpairmentChargesNetOfReversals_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_AdjustmentsForProvisionsIncludingExchangeDifferencesOnProvisions" xlink:to="label_riotintoplc_riotintoplcAdjustmentsForProvisionsIncludingExchangeDifferencesOnProvisions_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_PensionSettlement" xlink:to="label_riotintoplc_riotintoplcPensionSettlement_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_AdjustmentsForUtilisationOfProvisions" xlink:to="label_riotintoplc_riotintoplcAdjustmentsForUtilisationOfProvisions_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_NetProceedsFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio" xlink:to="label_riotintoplc_riotintoplcNetProceedsFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_NetPurchaseFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio" xlink:to="label_riotintoplc_riotintoplcNetPurchaseFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_OtherCashOutflowRelatingToPaymentsIntoTrustFund" xlink:to="label_riotintoplc_riotintoplcOtherCashOutflowRelatingToPaymentsIntoTrustFund_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_TotalAmountHeldInTrustFund" xlink:to="label_riotintoplc_riotintoplcTotalAmountHeldInTrustFund_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_DebtSecuritiesIssued" xlink:to="label_riotintoplc_riotintoplcDebtSecuritiesIssued_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_NominalValueOfBondBuyBackProgramme" xlink:to="label_riotintoplc_riotintoplcNominalValueOfBondBuyBackProgramme_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_NetCashOutflowFromRepaymentOfBond" xlink:to="label_riotintoplc_riotintoplcNetCashOutflowFromRepaymentOfBond_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_NominalValueOfBondRepaid" xlink:to="label_riotintoplc_riotintoplcNominalValueOfBondRepaid_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_TotalCashOutflowFromRepaymentOfBorrowings" xlink:to="label_riotintoplc_riotintoplcTotalCashOutflowFromRepaymentOfBorrowings_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_TaxPaymentRequired" xlink:to="label_riotintoplc_riotintoplcTaxPaymentRequired_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_GainOnRecognitionIncludedInOtherItems" xlink:to="label_riotintoplc_riotintoplcGainOnRecognitionIncludedInOtherItems_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_CurrentBorrowingsAndOtherFinancialLiabilities" xlink:to="label_riotintoplc_riotintoplcCurrentBorrowingsAndOtherFinancialLiabilities_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_NoncurrentBorrowingsAndOtherFinancialLiabilities" xlink:to="label_riotintoplc_riotintoplcNoncurrentBorrowingsAndOtherFinancialLiabilities_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_ShareCapitalRioTintoPlc" xlink:to="label_riotintoplc_riotintoplcShareCapitalRioTintoPlc_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_ShareCapitalRioTintoLimited" xlink:to="label_riotintoplc_riotintoplcShareCapitalRioTintoLimited_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_CurrencyTranslationArisingOnRioTintoLimitedsShareCapital" xlink:to="label_riotintoplc_riotintoplcCurrencyTranslationArisingOnRioTintoLimitedsShareCapital_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_OwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareAwardsToEmployees" xlink:to="label_riotintoplc_riotintoplcOwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareAwardsToEmployees_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_ChangeInEquityInterestHeldByRioTinto" xlink:to="label_riotintoplc_riotintoplcChangeInEquityInterestHeldByRioTinto_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_ShareBuyBack" xlink:to="label_riotintoplc_riotintoplcShareBuyBack_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_CompaniesNoLongerConsolidated" xlink:to="label_riotintoplc_riotintoplcCompaniesNoLongerConsolidated_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <labelArc xlink:type="arc" xlink:from="riotintoplc_OwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareOptions" xlink:to="label_riotintoplc_riotintoplcOwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareOptions_Standard" order="1" xlink:arcrole="http://www.xbrl.org/2003/arcrole/concept-label" />
    <label xlink:label="label_riotintoplc_riotintoplcImpairmentChargesNetOfReversals_Standard" id="riotintoplc_riotintoplcImpairmentChargesNetOfReversals_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Impairment charges net of reversals</label>
    <label xlink:label="label_riotintoplc_riotintoplcProfitRelatingToInterestsInUndevelopedProjects_Standard" id="riotintoplc_riotintoplcProfitRelatingToInterestsInUndevelopedProjects_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Profit relating to interests in undeveloped projects </label>
    <label xlink:label="label_riotintoplc_riotintoplcImpairmentOfInvestmentsInEquityAccountedUnits_Standard" id="riotintoplc_riotintoplcImpairmentOfInvestmentsInEquityAccountedUnits_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Impairment of investments in equity accounted units</label>
    <label xlink:label="label_riotintoplc_riotintoplcProfitBeforeFinanceItemsAndTaxation_Standard" id="riotintoplc_riotintoplcProfitBeforeFinanceItemsAndTaxation_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Profit before finance items and taxation</label>
    <label xlink:label="label_riotintoplc_riotintoplcNetChangeInCostsOfHedging_Standard" id="riotintoplc_riotintoplcNetChangeInCostsOfHedging_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Net change in costs of hedging</label>
    <label xlink:label="label_riotintoplc_riotintoplcCurrencyTranslationCharge_Standard" id="riotintoplc_riotintoplcCurrencyTranslationCharge_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Currency translation charge</label>
    <label xlink:label="label_riotintoplc_riotintoplcCashFlowsFromConsolidatedOperations_Standard" id="riotintoplc_riotintoplcCashFlowsFromConsolidatedOperations_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Cash flows from consolidated operations</label>
    <label xlink:label="label_riotintoplc_riotintoplcCashFlowsBeforeFinancingActivities_Standard" id="riotintoplc_riotintoplcCashFlowsBeforeFinancingActivities_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Cash flows before financing activities</label>
    <label xlink:label="label_riotintoplc_riotintoplcAdjustmentsForImpairmentChargesOfInvestmentsInEquityAccountedUnitsAfterTax_Standard" id="riotintoplc_riotintoplcAdjustmentsForImpairmentChargesOfInvestmentsInEquityAccountedUnitsAfterTax_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Adjustments for impairment charges of investments in equity accounted units after tax</label>
    <label xlink:label="label_riotintoplc_riotintoplcAdjustmentsForImpairmentChargesNetOfReversals_Standard" id="riotintoplc_riotintoplcAdjustmentsForImpairmentChargesNetOfReversals_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Adjustments for impairment charges net of reversals</label>
    <label xlink:label="label_riotintoplc_riotintoplcAdjustmentsForProvisionsIncludingExchangeDifferencesOnProvisions_Standard" id="riotintoplc_riotintoplcAdjustmentsForProvisionsIncludingExchangeDifferencesOnProvisions_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Adjustments for provisions (including exchange differences on provisions)</label>
    <label xlink:label="label_riotintoplc_riotintoplcPensionSettlement_Standard" id="riotintoplc_riotintoplcPensionSettlement_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">– Pension settlement</label>
    <label xlink:label="label_riotintoplc_riotintoplcAdjustmentsForUtilisationOfProvisions_Standard" id="riotintoplc_riotintoplcAdjustmentsForUtilisationOfProvisions_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Adjustments for utilisation of provisions</label>
    <label xlink:label="label_riotintoplc_riotintoplcNetProceedsFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio_Standard" id="riotintoplc_riotintoplcNetProceedsFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Net proceeds from sales and purchases of investments within separately managed portfolio</label>
    <label xlink:label="label_riotintoplc_riotintoplcNetPurchaseFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio_Standard" id="riotintoplc_riotintoplcNetPurchaseFromSalesAndPurchasesOfInvestmentsWithinSeparatelyManagedPortfolio_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Net purchase from sales and purchases of investments within separately managed portfolio</label>
    <label xlink:label="label_riotintoplc_riotintoplcOtherCashOutflowRelatingToPaymentsIntoTrustFund_Standard" id="riotintoplc_riotintoplcOtherCashOutflowRelatingToPaymentsIntoTrustFund_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Other cash outflow relating to payments into trust fund</label>
    <label xlink:label="label_riotintoplc_riotintoplcTotalAmountHeldInTrustFund_Standard" id="riotintoplc_riotintoplcTotalAmountHeldInTrustFund_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Total amount held in trust fund</label>
    <label xlink:label="label_riotintoplc_riotintoplcDebtSecuritiesIssued_Standard" id="riotintoplc_riotintoplcDebtSecuritiesIssued_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Debt securities issued</label>
    <label xlink:label="label_riotintoplc_riotintoplcNominalValueOfBondBuyBackProgramme_Standard" id="riotintoplc_riotintoplcNominalValueOfBondBuyBackProgramme_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Nominal value of bond buy-back programme</label>
    <label xlink:label="label_riotintoplc_riotintoplcNetCashOutflowFromRepaymentOfBond_Standard" id="riotintoplc_riotintoplcNetCashOutflowFromRepaymentOfBond_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Net cash outflow from repayment of bond</label>
    <label xlink:label="label_riotintoplc_riotintoplcNominalValueOfBondRepaid_Standard" id="riotintoplc_riotintoplcNominalValueOfBondRepaid_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Nominal value of bond repaid</label>
    <label xlink:label="label_riotintoplc_riotintoplcTotalCashOutflowFromRepaymentOfBorrowings_Standard" id="riotintoplc_riotintoplcTotalCashOutflowFromRepaymentOfBorrowings_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Total cash outflow from repayment of borrowings</label>
    <label xlink:label="label_riotintoplc_riotintoplcTaxPaymentRequired_Standard" id="riotintoplc_riotintoplcTaxPaymentRequired_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Tax payment required</label>
    <label xlink:label="label_riotintoplc_riotintoplcGainOnRecognitionIncludedInOtherItems_Standard" id="riotintoplc_riotintoplcGainOnRecognitionIncludedInOtherItems_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Gain on recognition included in other items</label>
    <label xlink:label="label_riotintoplc_riotintoplcCurrentBorrowingsAndOtherFinancialLiabilities_Standard" id="riotintoplc_riotintoplcCurrentBorrowingsAndOtherFinancialLiabilities_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Current borrowings and other financial liabilities</label>
    <label xlink:label="label_riotintoplc_riotintoplcNoncurrentBorrowingsAndOtherFinancialLiabilities_Standard" id="riotintoplc_riotintoplcNoncurrentBorrowingsAndOtherFinancialLiabilities_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Non-current borrowings and other financial liabilities</label>
    <label xlink:label="label_riotintoplc_riotintoplcShareCapitalRioTintoPlc_Standard" id="riotintoplc_riotintoplcShareCapitalRioTintoPlc_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Share Capital – Rio Tinto plc</label>
    <label xlink:label="label_riotintoplc_riotintoplcShareCapitalRioTintoLimited_Standard" id="riotintoplc_riotintoplcShareCapitalRioTintoLimited_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Share Capital – Rio Tinto Limited </label>
    <label xlink:label="label_riotintoplc_riotintoplcCurrencyTranslationArisingOnRioTintoLimitedsShareCapital_Standard" id="riotintoplc_riotintoplcCurrencyTranslationArisingOnRioTintoLimitedsShareCapital_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Currency translation arising on Rio Tinto Limited's share capital</label>
    <label xlink:label="label_riotintoplc_riotintoplcOwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareAwardsToEmployees_Standard" id="riotintoplc_riotintoplcOwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareAwardsToEmployees_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Own shares purchased from Rio Tinto shareholders to satisfy share awards to employees</label>
    <label xlink:label="label_riotintoplc_riotintoplcChangeInEquityInterestHeldByRioTinto_Standard" id="riotintoplc_riotintoplcChangeInEquityInterestHeldByRioTinto_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Change in equity interest held by Rio Tinto</label>
    <label xlink:label="label_riotintoplc_riotintoplcShareBuyBack_Standard" id="riotintoplc_riotintoplcShareBuyBack_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Share buy-back</label>
    <label xlink:label="label_riotintoplc_riotintoplcCompaniesNoLongerConsolidated_Standard" id="riotintoplc_riotintoplcCompaniesNoLongerConsolidated_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Companies no longer consolidated</label>
    <label xlink:label="label_riotintoplc_riotintoplcOwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareOptions_Standard" id="riotintoplc_riotintoplcOwnSharesPurchasedFromRioTintoShareholdersToSatisfyShareOptions_Standard" xlink:role="http://www.xbrl.org/2003/role/label" xlink:type="resource" xml:lang="en">Own shares purchased from Rio Tinto shareholders to satisfy share options</label>
  </labelLink>
</linkbase>